Skip to main content

2024 | OriginalPaper | Buchkapitel

Atomically Precise Electrocatalysts: Single/Dual/Multi-atom Catalysts

verfasst von : Sunil Kumar Baburao Mane, Naghma Shaishta

Erschienen in: Atomically Precise Electrocatalysts for Electrochemical Energy Applications

Verlag: Springer Nature Switzerland

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A possible strategy is to create electrochemical methods of conversion that may utilize renewable energy to transform airborne molecules like water, nitrogen, and carbon dioxide into commodities with value added. Due to their ability to influence the rate, effectiveness, and specificity of chemical transformation responses, electrocatalysts serve a vital part in these processes. The generation of energy that is environmentally friendly relies heavily on electrochemical energy transformations. Nevertheless, the outcome falls short of expectations since there are no highly effective and reliable electrocatalysts. Because of their high operation, stability, and potential to maximize utilization effectiveness, single, dual, and multi-atom catalysts have recently become hot study subjects in the field of electrocatalysis. The synthesis, characterization, and computer modeling of nanoscale materials have seen ongoing advancements. Hence the present book chapter discusses the important electrocatalytic applications of atomically precise Single/Dual/Multi-atom catalysts toward electrochemical energy applications. We expect that this chapter can offer perspectives for logical planning and effective formulation of improved electrocatalysts with atomic precision by examining structure–activity/stability correlations and electrochemical processes of diverse atomically precise electrocatalysts.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Chengcheng Q, Yuhua L, Yongping D (2023) Synergistic effects of Fe–Se dual single-atom sites for boosting electrochemical nonenzymatic H2O2 sensing. Appl Surf Sci 637:157900CrossRef Chengcheng Q, Yuhua L, Yongping D (2023) Synergistic effects of Fe–Se dual single-atom sites for boosting electrochemical nonenzymatic H2O2 sensing. Appl Surf Sci 637:157900CrossRef
Zurück zum Zitat Cui T, Wang YP, Ye T, Wu J, Chen Z, Li J, Lei Y, Wang D, Li Y (2022) Engineering dual single-atom sites on 2D ultrathin N-doped carbon nanosheets attaining ultra-low-temperature zinc-air battery. Angew Chem Int Ed Engl 61:e202115219CrossRef Cui T, Wang YP, Ye T, Wu J, Chen Z, Li J, Lei Y, Wang D, Li Y (2022) Engineering dual single-atom sites on 2D ultrathin N-doped carbon nanosheets attaining ultra-low-temperature zinc-air battery. Angew Chem Int Ed Engl 61:e202115219CrossRef
Zurück zum Zitat Dewei Z, Oleg VP, Lai X (2023) Design of a four-atom cluster embedded in carbon nitride for electrocatalytic generation of multi-carbon products. J Am Chem Soc 145:7030–7039CrossRef Dewei Z, Oleg VP, Lai X (2023) Design of a four-atom cluster embedded in carbon nitride for electrocatalytic generation of multi-carbon products. J Am Chem Soc 145:7030–7039CrossRef
Zurück zum Zitat Du L, Prabhakaran V, Xie X, Park S, Wang Y, Shao Y (2021) Low-PGM and PGM-free catalysts for proton exchange membrane fuel cells: stability challenges and material solutions. Adv Mater 33:1908232CrossRef Du L, Prabhakaran V, Xie X, Park S, Wang Y, Shao Y (2021) Low-PGM and PGM-free catalysts for proton exchange membrane fuel cells: stability challenges and material solutions. Adv Mater 33:1908232CrossRef
Zurück zum Zitat Guodong S, Yanan C, Deqing L, Mingzhen H, Xinhu L, Zhe W, Zengjian C, Fengyi S, Bozhen C, Kebin Z (2023) Dual-atom Cu2/N-doped carbon catalyst for electroreduction of CO2 to C2H4. Appl Catal a: General 651:119025CrossRef Guodong S, Yanan C, Deqing L, Mingzhen H, Xinhu L, Zhe W, Zengjian C, Fengyi S, Bozhen C, Kebin Z (2023) Dual-atom Cu2/N-doped carbon catalyst for electroreduction of CO2 to C2H4. Appl Catal a: General 651:119025CrossRef
Zurück zum Zitat Hao L, Wenfu X, Baotao K, Jin YL (2023) Understanding the synergistic effects of dual-atom catalysts NiSn on carbon dioxide reduction. Appl Surf Sci 638:158109CrossRef Hao L, Wenfu X, Baotao K, Jin YL (2023) Understanding the synergistic effects of dual-atom catalysts NiSn on carbon dioxide reduction. Appl Surf Sci 638:158109CrossRef
Zurück zum Zitat He Z, Kuang H, Alex WR, Angus IK, Dongwook K, Jisoon I, Euijoon Y, Gun-Do L, Jamie HW (2014) Atomic structure and dynamics of metal dopant pairs in graphene. Nano Lett 14:3766–3772CrossRef He Z, Kuang H, Alex WR, Angus IK, Dongwook K, Jisoon I, Euijoon Y, Gun-Do L, Jamie HW (2014) Atomic structure and dynamics of metal dopant pairs in graphene. Nano Lett 14:3766–3772CrossRef
Zurück zum Zitat Hoki S, Ji-Hwan L, Periyayya U, Vandung D, Aloysius S, Yeji L, In-Hwan L (2023) Platinum single-atom catalysts anchored on a heterostructure cupric oxide/copper foam for accelerating photoelectrochemical hydrogen evolution reaction. Nano Energy 117:108904CrossRef Hoki S, Ji-Hwan L, Periyayya U, Vandung D, Aloysius S, Yeji L, In-Hwan L (2023) Platinum single-atom catalysts anchored on a heterostructure cupric oxide/copper foam for accelerating photoelectrochemical hydrogen evolution reaction. Nano Energy 117:108904CrossRef
Zurück zum Zitat Hongwei Z, Xindie J, Jong-Min L, Xin W (2022) Tailoring of active sites from single to dual atom sites for highly efficient electrocatalysis. ACS Nano 16:17572–17592CrossRef Hongwei Z, Xindie J, Jong-Min L, Xin W (2022) Tailoring of active sites from single to dual atom sites for highly efficient electrocatalysis. ACS Nano 16:17572–17592CrossRef
Zurück zum Zitat Huang J, Sementa L, Liu Z, Barcaro G, Feng M, Liu E, Jiao L, Xu M, Leshchev D, Lee SJ, Mufan L, Chengzhang W, Enbo Z, Yang L, Bosi P, Xiangfeng D, William A. Goddard III, Alessandro F, Qingying J, Yu H (2022) Experimental Sabatier plot for predictive design of active and stable Pt-alloy oxygen reduction reaction catalysts. Nat Catal 5:513–523 Huang J, Sementa L, Liu Z, Barcaro G, Feng M, Liu E, Jiao L, Xu M, Leshchev D, Lee SJ, Mufan L, Chengzhang W, Enbo Z, Yang L, Bosi P, Xiangfeng D, William A. Goddard III, Alessandro F, Qingying J, Yu H (2022) Experimental Sabatier plot for predictive design of active and stable Pt-alloy oxygen reduction reaction catalysts. Nat Catal 5:513–523
Zurück zum Zitat Jia L, Qiuyun Z, Mufei Y, Siguo C, Jianghai D, Xinyu P, Yan L, Jing L, Qiang L, Minhua S, Zidong W (2021) Cross-linked multi-atom Pt catalyst for highly efficient oxygen reduction catalysis. Appl Catal B 284:119728CrossRef Jia L, Qiuyun Z, Mufei Y, Siguo C, Jianghai D, Xinyu P, Yan L, Jing L, Qiang L, Minhua S, Zidong W (2021) Cross-linked multi-atom Pt catalyst for highly efficient oxygen reduction catalysis. Appl Catal B 284:119728CrossRef
Zurück zum Zitat Jiang K, Zhao J, Wang H (2020) Catalyst design for electrochemical oxygen reduction toward hydrogen peroxide. Adv Funct Mater 30:2003321CrossRef Jiang K, Zhao J, Wang H (2020) Catalyst design for electrochemical oxygen reduction toward hydrogen peroxide. Adv Funct Mater 30:2003321CrossRef
Zurück zum Zitat Jiawen G, Huimin L, Dezheng L, Jian W, Xavier D, Dehua H, Qijian Z (2022) A mini review on the synthesis of single atom catalysts. RSC Adv 12:9373–9394CrossRef Jiawen G, Huimin L, Dezheng L, Jian W, Xavier D, Dehua H, Qijian Z (2022) A mini review on the synthesis of single atom catalysts. RSC Adv 12:9373–9394CrossRef
Zurück zum Zitat Jiazhan L, Chang C, Lekai X, Yu Z, Wei W, Erbo Z, Yue W, Chen C (2023) Challenges and perspectives of single-atom-based catalysts for electrochemical reactions. JACS Au 3(3):736–755CrossRef Jiazhan L, Chang C, Lekai X, Yu Z, Wei W, Erbo Z, Yue W, Chen C (2023) Challenges and perspectives of single-atom-based catalysts for electrochemical reactions. JACS Au 3(3):736–755CrossRef
Zurück zum Zitat Juan M, Jingmin W, Zhen L, Xiaoying F, Ning Z, Xinquan Z, Hang X, Xuefeng W, Shuge P (2023) Single-atom Pd loaded on nitrogen-doped carbon as a bifunctional catalyst for the electrochemical degradation of 2,4-dichlorophenol. J Environ Chem Eng 11:111007CrossRef Juan M, Jingmin W, Zhen L, Xiaoying F, Ning Z, Xinquan Z, Hang X, Xuefeng W, Shuge P (2023) Single-atom Pd loaded on nitrogen-doped carbon as a bifunctional catalyst for the electrochemical degradation of 2,4-dichlorophenol. J Environ Chem Eng 11:111007CrossRef
Zurück zum Zitat Junhong F, Jinhu D, Rui S, Keju S, Junying Z, Mingrun L, Nana Y, Bingsen Z, Mark GH, Qiang F, Jiahui H (2021) ACS Catal 11:1952–1961 Junhong F, Jinhu D, Rui S, Keju S, Junying Z, Mingrun L, Nana Y, Bingsen Z, Mark GH, Qiang F, Jiahui H (2021) ACS Catal 11:1952–1961
Zurück zum Zitat Kulkarni A, Siahrostami S, Patel A, Nørskov JK (2018) Understanding catalytic activity trends in the oxygen reduction reaction. Chem Rev 118:2302–2312CrossRef Kulkarni A, Siahrostami S, Patel A, Nørskov JK (2018) Understanding catalytic activity trends in the oxygen reduction reaction. Chem Rev 118:2302–2312CrossRef
Zurück zum Zitat Lei Y, Shenghua F, Weihua Z (2023) Achieving reaction pathway separation for electrochemical nitrate fixation on triatomic catalysts: a new mechanism. J Hazard Mater 441:129972CrossRef Lei Y, Shenghua F, Weihua Z (2023) Achieving reaction pathway separation for electrochemical nitrate fixation on triatomic catalysts: a new mechanism. J Hazard Mater 441:129972CrossRef
Zurück zum Zitat Li R, Wang D (2022) Superiority of dual-atom catalysts in electrocatalysis: one step further than single-atom catalysts. Adv Energy Mater 12:2103564CrossRef Li R, Wang D (2022) Superiority of dual-atom catalysts in electrocatalysis: one step further than single-atom catalysts. Adv Energy Mater 12:2103564CrossRef
Zurück zum Zitat Li Y, Panpan L, Qingyi Z, Anuj K, Kai S, Shubo T, Xiaoming S (2023) Atomically precise electrocatalysts for oxygen reduction reaction. Chem 9:280–342CrossRef Li Y, Panpan L, Qingyi Z, Anuj K, Kai S, Shubo T, Xiaoming S (2023) Atomically precise electrocatalysts for oxygen reduction reaction. Chem 9:280–342CrossRef
Zurück zum Zitat Libo S, Vikas R, Xin W (2022) Multi-atom cluster catalysts for efficient electrocatalysis. Chem Soc Rev 51:8923–8956CrossRef Libo S, Vikas R, Xin W (2022) Multi-atom cluster catalysts for efficient electrocatalysis. Chem Soc Rev 51:8923–8956CrossRef
Zurück zum Zitat Ling-Chan T, Jin-Nian H, Yang M, Jin-Xia L, Chun Z, Jun L (2023) Ultrastable nickel single-atom catalysts with high activity and selectivity for electrocatalytic CO2 methanation. Nano Res 16:8987–8995CrossRef Ling-Chan T, Jin-Nian H, Yang M, Jin-Xia L, Chun Z, Jun L (2023) Ultrastable nickel single-atom catalysts with high activity and selectivity for electrocatalytic CO2 methanation. Nano Res 16:8987–8995CrossRef
Zurück zum Zitat Liu J, Wan X, Liu S, Liu X, Zheng L, Yu R, Shui J (2021) Hydrogen passivation of M–N–C (M = Fe, Co) catalysts for storage stability and ORR activity improvements. Adv Mater 33:2103600CrossRef Liu J, Wan X, Liu S, Liu X, Zheng L, Yu R, Shui J (2021) Hydrogen passivation of M–N–C (M = Fe, Co) catalysts for storage stability and ORR activity improvements. Adv Mater 33:2103600CrossRef
Zurück zum Zitat Meng FC, Peng M, Chen Y, Cai X, Huang F, Yang L, Liu X, Li T, Wen X, Wang N, Dequan X, Hong J, Lixin X, Hongyang L, Ding M (2022) Defect-rich graphene stabilized atomically dispersed Cu3 clusters with enhanced oxidase-like activity for antibacterial applications. Appl Catal B 301:120826 Meng FC, Peng M, Chen Y, Cai X, Huang F, Yang L, Liu X, Li T, Wen X, Wang N, Dequan X, Hong J, Lixin X, Hongyang L, Ding M (2022) Defect-rich graphene stabilized atomically dispersed Cu3 clusters with enhanced oxidase-like activity for antibacterial applications. Appl Catal B 301:120826
Zurück zum Zitat Mengmeng F, Jiewu C, Jingjie W, Robert V, Dongping S, Pulickel MA (2020) Improving the catalytic activity of carbon-supported single atom catalysts by polynary metal or heteroatom doping. Small 16:1906782CrossRef Mengmeng F, Jiewu C, Jingjie W, Robert V, Dongping S, Pulickel MA (2020) Improving the catalytic activity of carbon-supported single atom catalysts by polynary metal or heteroatom doping. Small 16:1906782CrossRef
Zurück zum Zitat Nishant B, Plaban JS, Satyajit DB, Nand Kishor G, Ramesh CD (2020) Catalytic oxidation of NO on [Au–M]−(M = Pd and Pt) bimetallic dimers: an insight from density functional theory approach. J Phys Chem C 124:3059–3068CrossRef Nishant B, Plaban JS, Satyajit DB, Nand Kishor G, Ramesh CD (2020) Catalytic oxidation of NO on [Au–M]−(M = Pd and Pt) bimetallic dimers: an insight from density functional theory approach. J Phys Chem C 124:3059–3068CrossRef
Zurück zum Zitat Priyanka A, Debasish S, Kamlendra A, Prashanth WM (2022) Functional role of single-atom catalysts in electrocatalytic hydrogen evolution: current developments and future challenges. Coord Chem Rev 452:214289CrossRef Priyanka A, Debasish S, Kamlendra A, Prashanth WM (2022) Functional role of single-atom catalysts in electrocatalytic hydrogen evolution: current developments and future challenges. Coord Chem Rev 452:214289CrossRef
Zurück zum Zitat Qiao B, Wang A, Yang X, Allard LF, Jiang Z, Cui Y, Liu J, Li J, Zhang T (2011) Single-atom catalysis of CO oxidation using Pt1/FeOx. Nat Chem 3:634–641 Qiao B, Wang A, Yang X, Allard LF, Jiang Z, Cui Y, Liu J, Li J, Zhang T (2011) Single-atom catalysis of CO oxidation using Pt1/FeOx. Nat Chem 3:634–641
Zurück zum Zitat Qingchun Z, Di L, Yaping Z, Zhiliang G, Minpeng C, Yuyun C, Bo J, Yingze S, Hui P (2023) Insight into coupled Ni–Co dual-metal atom catalysts for efficient synergistic electrochemical CO2 reduction. J Energy Chem 87:509–517CrossRef Qingchun Z, Di L, Yaping Z, Zhiliang G, Minpeng C, Yuyun C, Bo J, Yingze S, Hui P (2023) Insight into coupled Ni–Co dual-metal atom catalysts for efficient synergistic electrochemical CO2 reduction. J Energy Chem 87:509–517CrossRef
Zurück zum Zitat Wang Y, Chu F, Zeng J, Wang Q, Naren T, Li Y, Cheng Y, Lei Y, Wu F (2021) Single atom catalysts for fuel cells and rechargeable batteries: principles, advances, and opportunities. ACS Nano 15:210–239CrossRef Wang Y, Chu F, Zeng J, Wang Q, Naren T, Li Y, Cheng Y, Lei Y, Wu F (2021) Single atom catalysts for fuel cells and rechargeable batteries: principles, advances, and opportunities. ACS Nano 15:210–239CrossRef
Zurück zum Zitat Wang Y, Wan X, Liu J, Li W, Li Y, Guo X, Liu X, Shang J, Shui J (2022) Catalysis stability enhancement of Fe/Co dual-atom site via phosphorus coordination for proton exchange membrane fuel cell. Nano Res 15:3082–3089CrossRef Wang Y, Wan X, Liu J, Li W, Li Y, Guo X, Liu X, Shang J, Shui J (2022) Catalysis stability enhancement of Fe/Co dual-atom site via phosphorus coordination for proton exchange membrane fuel cell. Nano Res 15:3082–3089CrossRef
Zurück zum Zitat Wang J, Gan L, Zhang W, Peng Y, Yu H, Yan Q, Xia X, Wang X (2018) In situ formation of molecular Ni–Fe active sites on heteroatom-doped graphene as a heterogeneous electrocatalyst toward oxygen evolution. Sci Adv 4:eaap7970 Wang J, Gan L, Zhang W, Peng Y, Yu H, Yan Q, Xia X, Wang X (2018) In situ formation of molecular Ni–Fe active sites on heteroatom-doped graphene as a heterogeneous electrocatalyst toward oxygen evolution. Sci Adv 4:eaap7970
Zurück zum Zitat Weiyu Z, Yuguang C, Wenshu Z, Jinhui Z, Fan L, Kai W, Fangxu L, Heng L, Jing L, Meiping T, Erkang W, Shaojun G (2021) Emerging dual-atomic-site catalysts for efficient energy catalysis. Adv Mater 33:2102576CrossRef Weiyu Z, Yuguang C, Wenshu Z, Jinhui Z, Fan L, Kai W, Fangxu L, Heng L, Jing L, Meiping T, Erkang W, Shaojun G (2021) Emerging dual-atomic-site catalysts for efficient energy catalysis. Adv Mater 33:2102576CrossRef
Zurück zum Zitat Xia W, Mahmood A, Liang Z, Zou R, Guo S (2016) Earth-abundant nanomaterials for oxygen reduction. Angew Chem Int Ed Engl 55:2650–2676CrossRef Xia W, Mahmood A, Liang Z, Zou R, Guo S (2016) Earth-abundant nanomaterials for oxygen reduction. Angew Chem Int Ed Engl 55:2650–2676CrossRef
Zurück zum Zitat Xiang-Ming L, Hong-Juan W, Chao Z, Di-Chang Z, Tong-Bu L (2023) Controlled synthesis of a Ni2 dual-atom catalyst for synergistic CO2 electroreduction. Appl Catal B 322:122073CrossRef Xiang-Ming L, Hong-Juan W, Chao Z, Di-Chang Z, Tong-Bu L (2023) Controlled synthesis of a Ni2 dual-atom catalyst for synergistic CO2 electroreduction. Appl Catal B 322:122073CrossRef
Zurück zum Zitat Yang C, Jian L, Qin P, Xu L, Tianyi M, Xiaodong W (2023) Inter-metal interaction of dual-atom catalysts in heterogeneous catalysis. Angew Chem Int Ed 62:e202306469CrossRef Yang C, Jian L, Qin P, Xu L, Tianyi M, Xiaodong W (2023) Inter-metal interaction of dual-atom catalysts in heterogeneous catalysis. Angew Chem Int Ed 62:e202306469CrossRef
Zurück zum Zitat Yuan S, Zhang J, Hu L, Li J, Li S, Gao Y, Zhang Q, Gu L, Yang W, Feng X. Wang B (2021) Decarboxylation-induced defects in MOF-derived single cobalt atom@carbon electrocatalysts for efficient oxygen reduction. Angew Chem Int Ed Engl 60:21685–21690 Yuan S, Zhang J, Hu L, Li J, Li S, Gao Y, Zhang Q, Gu L, Yang W, Feng X. Wang B (2021) Decarboxylation-induced defects in MOF-derived single cobalt atom@carbon electrocatalysts for efficient oxygen reduction. Angew Chem Int Ed Engl 60:21685–21690
Metadaten
Titel
Atomically Precise Electrocatalysts: Single/Dual/Multi-atom Catalysts
verfasst von
Sunil Kumar Baburao Mane
Naghma Shaishta
Copyright-Jahr
2024
DOI
https://doi.org/10.1007/978-3-031-54622-8_2