nach oben

Erschienen in:

2024 | OriginalPaper | Buchkapitel

Electrocatalytic Properties of Atomically Precise Electrocatalysts

verfasst von : Kalaiarasi Senthurpandi, Kirupagaran Ramar, Karpagavinayagam Petchimuthu, Vedhi Chinnapaiyan

Erschienen in: Atomically Precise Electrocatalysts for Electrochemical Energy Applications

Verlag: Springer Nature Switzerland

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A well-defined model nanocatalyst is absolutely necessary to reveal the detailed mechanism of electro-catalysis and thereby to lead to the development of a new efficient electro-catalyst. Atomically regulated metal nanoclusters will allow us to systematically optimize the electrochemical and surface properties suitable for electro-catalysis, giving a potent platform for precisely tuned electro-catalysis. Nanoclusters are made up of metal atoms and ligands with diameters ranging from 2 to 3 nm. Gold nanoclusters with precise atomic numbers have received a lot of attention due to their stability and unusual structure. More new ways for synthesizing atomically accurate gold nanoclusters have been developed as a result of more extensive research on gold nanoclusters. Recent advances in the electrochemistry of atomically accurate metal nanoclusters and their applications in electro-catalysis are discussed in this account. Other metal nanoclusters have made far less progress in electrochemical investigations than gold nanoclusters; hence, this chapter focuses on electro-catalyst applications of metal-based nanoclusters. Voltammetry has proven to be particularly effective in studying the electrical structure of metal nanoclusters.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Role of Electrocatalysts in Electrochemical Energy Conversion and Storage Devices

Nächstes Kapitel Electrochemical Energy Conversion and Storage Strategies

Aet Y (2023) Covalence bridge atomically precise metal nanocluster and metal-organic frameworks for enhanced photostability and photocatalysis. Nano Res 16:1527–1532CrossRef

Antoine R (2020) Supramolecular gold chemistry: from atomically precise thiolateprotected gold nanoclusters to gold-thiolate nanostructures. Nanomaterials 10:377CrossRef

Artero V, Chavarot-Kerlidou M, Fontecave M (2011) Splitting water with cobalt. AngewandteChemie Int Ed 50(32):7238–7266CrossRef

Bard AJ, Faulkner LR (2001) Electrochemical methods: fundamentals and applications, 2nd edn. Hoboken, NJ. ISBN 0-471-04372-9. OCLC 43859504

Bard AJ, Faulkner LR (2001b) Electrochemical methods: fundamentals and applications. Wiley, New York

Brown MD, Schoenfisch MH (2019) Electrochemical nitric oxide sensors: principles of design and characterization. Chem Rev 119(22):11551–11575CrossRef

Carmo M, Fritz DL, Mergel J, Stolten D (2013) A comprehensive review on PEM water electrolysis. Int J Hydrogen Energy 38(12):4901–4934CrossRef

Chakraborty I, Pradeep T (2017) Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles. Chem Rev 117(12):8208–8271CrossRef

Chen W, Chen S (2009) Oxygen electroreduction catalyzed by gold nanoclusters: strong core size effects. Angew Chem Int Ed 48:4386–4389CrossRef

Chen H, Simoska O, Lim K, Grattieri M, Yuan M, Dong F, Lee YS, Beaver K, Weliwatte S, Gaffney EM, Minteer SD (2020) Fundamentals, applications, and future directions of bioelectrocatalysis. Chem Rev 120(23):12903–12993CrossRef

Dai L (2017) Carbon-based catalysts for metal-free electrocatalysis. Curr Opin Electrochem 4(1):18–25CrossRef

Debe MK (2012) Electrocatalyst approaches and challenges for automotive fuel cells. Nature 486(7401):43–51CrossRef

He X, Gao CY, Wang MX, Zhao L (2012) Designed synthesis of a metal cluster-pillared coordination cage. Chem Commun 48:10877–10879CrossRef

Hesari M, Ding ZA (2017) Grand avenue to au nanocluster electrochemiluminescence. Acc Chem Res 50:218–230CrossRef

Ito S, Takano S, Tsukuda T (2019) Alkynyl-protected Au22(C≡CR)18 clusters featuring new interfacial motifs and R-dependent photoluminescence. J Phys Chem Lett 10:6892–6896CrossRef

Jaramillo T (2014) Electrocatalysis 101 | GCEP Symposium

Jiao L, Wang Y, Jiang H-L, Xu Q (2017) Metal-organic frameworks as platforms for catalytic applications. Adv Mater 30(37):1703663CrossRef

Jin R (2010) Quantum sized, thiolate-protected gold nanoclusters. Nanoscale 2:343–362CrossRef

Jin R, Zeng C, Zhou M, Chen Y (2016) Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities. Chem Rev 116:10346–10413CrossRef

Kang X, Li Y, Zhu M, Jin R (2020) Atomically precise alloy nanoclusters: syntheses, structures, and properties. Chem Soc Rev 49:6443–6514CrossRef

Kleijn SEF, Lai SCS, Koper MTM, Unwin PR (2014) Electrochemistry of nanoparticles. AngewandteChemie Int Ed 53(14):3558–3586

Koper MTM (2011) Structure sensitivity and nanoscale effects in electro-catalysis. Nanoscale R Soc Chem 3(5):2054–2073CrossRef

Kotrel S, BrUninger S (2008) Industrial electrocatalysis. Handbook of Heterogeneous Catalysis

Lenne Q, Retout M, Gosselin B, Bruylants G, Jabin I, Hamon J, Lagrost C, Leroux YR (2020) Highly stable silver nanohybrid electrocatalysts for the oxygen reduction reaction. Chem Commun 58:3334–3337CrossRef

Levi-Kalisman Y, Jadzinsky PD, Kalisman N, Tsunoyama H, Tsukuda A, Bushnell KRD (2011) Synthesis and characterization of Au₁₀₂(p-MBA)₄₄ nanoparticles. J Am Chem Soc 133:2976–2982CrossRef

Li C, Chai OJH, Yao Q, Liu Z, Wang L, Wang H, Xie J (2021) Electrocatalysis of gold-based nanoparticles and nanoclusters. Mater Horiz 8:1657–1682CrossRef

Liu L, Corma A (2018) Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles. Chem Rev 118:4981–5079CrossRef

Lu Y, Jiang Y, Gao X, Chen W (2014) Charge state-dependent catalytic activity of [Au 25 (SC 12 H 25) 18] nanoclusters for the two-electron reduction of dioxygen to hydrogen peroxide. Chem Commun 50:8464–8467CrossRef

Luo M, Guo S (2017) Strain-controlled electro-catalysis on multimetallic nanomaterials. Nat Rev Mater 2(11):17059MathSciNetCrossRef

McCreery RL (2008) Advanced carbon electrode materials for molecular electrochemistry. Chem Rev 108(7):2646–2687CrossRef

Met Z (2009) Reversible switching of magnetism in thiolate-protected Au25 superatom. J Am Chem Soc 131:2490–2492CrossRef

Milton RD, Minteer SD (2019) Nitrogenase bioelectrochemistry for synthesis applications. Acc Chem Res 52(12):3351–3360CrossRef

Mistry H, Varela AS, Strasser P, Cuenya BR (2016) Nanostructured electro-catalysts with tunable activity and selectivity. Nat Rev Mater 1(4):1–14CrossRef

Qiao Y, Bao S-J, Li CM (2010) Electrocatalysis in microbial fuel cells—from electrode material to direct electrochemistry. Energy Environ Sci 3(5):544CrossRef

Seh Zhi W, Kibsgaard J, Dickens Colin F, Chorkendorff I, Norskov Jens K, Jaramillo Thomas F (2017) Combining theory and experiment in electrocatalysis: insights intomaterials design. Science 355(6321):eaad4998

Shang L, Xu J, Nienhaus GU (2019) Recent advances in synthesizing metal nanocluster-based nanocomposites for application in sensing, imaging and catalysis. Nano Today 28:100767CrossRef

Sharma RK, Yadav P, Yadav M, Gupta R, Rana P, Srivastava A, Zbořil R, Varma RS, Antonietti M, Gawande MB (2020) Recent development of covalent organic frameworks (COFs): synthesis and catalytic (organic-electro-photo) applications. Mater Horizons 7(2):411–454CrossRef

She ZW, Kibsgaard J, Dickens CF, Chorkendorff I, Nørskov JK, Jaramillo TF (2017) Combining theory and experiment in electro-catalysis: insights into materials design. Science 355:eaad4998

Shi Y, Lyu Z, Zhao M, Chen R, Nguyen QN, Xia Y (2021) Noble-metal nanocrystals with controlled shapes for catalytic and electrocatalytic applications. Chem Rev 121(2):649–735CrossRef

Sumner L, Sakthivel NA, Schrock H, Artyushkova K, Dass A, Chakraborty S (2018) Electrocatalytic oxygen reduction activities of thiol-protected nanomolecules ranging in size from Au₂₈(SR)₂₀ to Au₂₇₉(SR)₈₄. J Phys Chem C 122:24809–24817CrossRef

Tang Q, Lee Y, Li D-Y, Choi W, Liu CW, Lee D, Jiang D-E (2017) Lattice-hydride mechanism in electrocatalytic CO₂ reduction by structurally precise copper-hydride nanoclusters. J Am Chem Soc 139:9728–9736CrossRef

Templeton AC, Wuelfing WP, Murray RW (2000) Monolayer-protected cluster molecules. Acc Chem Res 33:27–36CrossRef

Tian S, Liao L, Yuan J, Yao C, Chen J, Yang J, Wu Z (2016) Structures and magnetism of mono-palladium and mono-platinum doped Au₂₅(PET)₁₈ nanoclusters. Chem Commun 52:9873–9876CrossRef

Walter M (2008) A unified view of ligand-protected gold clusters as super atom complexes. Proc Natl Acad Sci USA 105:9157–9162CrossRef

Wang X (2009) CNTs tuned to provide electro-catalyst support. Nanotechweb.org. Archived from the original on 22 2009

Wang S, Yu H, Zhu M (2015) [PDF] Noble and valuable: atomically precise gold nanoclusters. Sci China: Chem 59:206–208CrossRef

Wang L, Tang Z, Yan W, Yang H, Wang Q, Chen S (2016a) Porous carbon-supported gold nanoparticles for oxygen reduction reaction: effects of nanoparticle size. ACS Appl Mater Interfaces 8:20635–20641CrossRef

Wang Q, Wang L, Tang Z, Wang F, Yan W, Yang H, Zhou W, Li L, Kang X, Chen S (2016b) Hybrid nanomaterials based on graphene and gold nanoclusters for efficient electrocatalytic reduction of oxygen. Nanoscale 8:6629–6635CrossRef

Wildgoose GG, Banks CE, Leventis HC, Compton RG (2005) Chemically modified carbon nanotubes for use in electroanalysis. Microchimica Acta 152(3–4):187–214

Yamazoe S, Koyasu K, Tsukuda T (2014) Nonscalable oxidation catalysis of gold clusters. Acc Chem Res 47:816–824CrossRef

Yang JY, Kerr TA, Wang XS, Barlow JM (2020) Reducing co₂ to hco₂–at mild potentials: lessons from formate dehydrogenase. J Am Chem Soc 142(46):19438–19445CrossRef

Zeng C, Li T, Das A, Rosi NL, Jin R (2013) Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries. J Am Chem Soc 135:10011–10013CrossRef

Zhang Q, Zhang X, Wang J, Wang C (2021) Graphene-supported single-atom catalysts and applications in electrocatalysis. Nanotechnology 32(3):032001CrossRef

Zheng W, Liu M, Lee LYS (2020) Electrochemical instability of metal–organic frameworks: in situ spectroelectrochemical investigation of the real active sites. ACS Catal 10(1):81–92CrossRef

Zhu X, Chen L, Liu Y (2023) Atomically precise Au nanoclusters for electrochemical hydrogen evolution catalysis: progress and perspectives. Polyoxometalates 2(4):9140031CrossRef

Titel: Electrocatalytic Properties of Atomically Precise Electrocatalysts
verfasst von: Kalaiarasi Senthurpandi
Kirupagaran Ramar
Karpagavinayagam Petchimuthu
Vedhi Chinnapaiyan
Verlag: Springer Nature Switzerland
Buch: Atomically Precise Electrocatalysts for Electrochemical Energy Applications
Print ISBN: 978-3-031-54621-1

Electronic ISBN: 978-3-031-54622-8

Copyright-Jahr: 2024
DOI: https://doi.org/10.1007/978-3-031-54622-8_4