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2024 | OriginalPaper | Chapter

Dual-Atom Catalysts for Oxygen Evolution Reaction

Authors : Hamid Dehghan-Manshadi, Mohammad Mazloum-Ardakani, Soraya Ghayempour

Published in: Atomically Precise Electrocatalysts for Electrochemical Energy Applications

Publisher: Springer Nature Switzerland

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Abstract

Oxygen evolution reaction (OER) is a chemical reaction in the process of generating molecular oxygen in the oxidation of water during oxygenic photosynthesis, electrolysis of water into oxygen and hydrogen, and electrocatalytic oxygen evolution from oxides and oxoacids. Noble metal oxides such as ruthenium and iridium oxides have good electrocatalytic activity for the OER process, but they have disadvantages such as high cost, inaccessibility, limited reserves, and durability. Therefore, the design and preparation of a low-cost, highly active, and high stable performance catalyst is necessary. In this regard, dual-atom catalysts (DACs) are a suitable option according to their characterization such as good electrocatalytic activity, high atomic efficiency, and synergic effects. Their atomically dispersed active sites lead to maximum utilization efficiency of the metal sites. This chapter presents an outlook on the design, catalytic mechanism, and application of dual-atom catalysts in oxygen evolution reactions.

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Acar C, Dincer I (2018) 3.1 Hydrogen Production. In: Dincer I ed. Comprehensive energy systems. Elsevier, Oxford, p 1–40

Bai X, Guan J (2023) Applications of MXene-Based single-atom catalysts. Small Struct 4(7):2200354CrossRef

Bai L, Hsu C-S, Alexander DTL, Chen HM, Hu X (2019) A Cobalt-Iron Double-Atom catalyst for the oxygen evolution reaction. J Am Chem Soc 141(36):14190–14199CrossRef

Bai L, Hsu C-S, Alexander DTL, Chen HM, Hu X (2021) Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis. Nat Energy 6(11):1054–1066CrossRef

Chen S, Duan J, Jaroniec M, Qiao SZ (2013) Three-Dimensional N-Doped graphene Hydrogel/NiCo double hydroxide electrocatalysts for highly efficient oxygen evolution. Angew Chem Int Ed 52(51):13567–13570CrossRef

Chen M, Wang L, Yang H, Zhao S, Xu H, Wu G (2018) Nanocarbon/oxide composite catalysts for bifunctional oxygen reduction and evolution in reversible alkaline fuel cells: a mini review. J Power Sour 375:277–290CrossRef

Chen Y, Hu S, Nichols F, Bridges F, Kan S, He T et al (2020) Carbon aerogels with atomic dispersion of binary iron–cobalt sites as effective oxygen catalysts for flexible zinc–air batteries. J Mater Chem A 8(23):11649–11655CrossRef

Chen Z, Liao X, Sun C, Zhao K, Ye D, Li J et al (2021) Enhanced performance of atomically dispersed dual-site Fe–Mn electrocatalysts through cascade reaction mechanism. Appl Catal B 288:120021CrossRef

Cheng W, Lu XF, Luan D, Lou XW (2020) NiMn-Based bimetal-organic framework nanosheets supported on multi-channel carbon fibers for efficient oxygen electrocatalysis. Angew Chem Int Ed 59(41):18234–18239CrossRef

Cheng Y, He S, Veder J-P, De Marco R, Yang S-z, Ping Jiang S (2019) Atomically dispersed bimetallic FeNi catalysts as highly efficient bifunctional catalysts for reversible oxygen evolution and oxygen reduction reactions. ChemElectroChem 6(13):3478–87

Dehghan-Manshadi H, Mazloum-Ardakani M, Ghayempour S (2023) Polymer-Metal oxides nanocomposites for Metal-Ion batteries. Recent advancements in polymeric materials for electrochemical energy storage. Springer; pp 299–312

Flügel EA, Lau VWh, Schlomberg H, Glaum R, Lotsch BV (2016) Homonuclear mixed-valent cobalt imidazolate framework for oxygen-evolution electrocatalysis. Chem–A European J 22(11):3676–80

Ghosh SK, Rahaman H (2019) Chapter 16—noble metal-manganese oxide hybrid nanocatalysts. In: Mohapatra S, Nguyen TA, Nguyen-Tri P (eds) Noble metal-metal oxide hybrid nanoparticles. Woodhead Publishing, pp 313–340CrossRef

Han X, Ling X, Yu D, Xie D, Li L, Peng S et al (2019) Atomically dispersed binary Co-Ni sites in Nitrogen-Doped hollow Carbon Nanocubes for reversible oxygen reduction and evolution. Adv Mater 31(49):1905622CrossRef

He T, Santiago ARP, Kong Y, Ahsan MA, Luque R, Du A et al (2022) Atomically dispersed heteronuclear dual-atom catalysts: a new rising star in atomic catalysis. Small 18(12):2106091CrossRef

Hou C-C, Wang H-F, Li C, Xu Q (2020) From metal–organic frameworks to single/dual-atom and cluster metal catalysts for energy applications. Energy Environ Sci 13(6):1658–1693CrossRef

Hu R, Li Y, Zeng Q, Shang J (2020) Role of active sites in N-coordinated Fe-Co dual-metal doped graphene for oxygen reduction and evolution reactions: a theoretical insight. Appl Surf Sci 525:146588CrossRef

Huang S, Qiao Z, Sun P, Qiao K, Pei K, Yang L et al (2022) The strain induced synergistic catalysis of FeN4 and MnN3 dual-site catalysts for oxygen reduction in proton-/anion-exchange membrane fuel cells. Appl Catal B 317:121770CrossRef

Huang M, Meng H, Luo J, Li H, Feng Y, Xue X-X (2023) Understanding the activity and design principle of dual-atom catalysts supported on C₂N for oxygen reduction and evolution reactions: from homonuclear to heteronuclear. J Phys Chem Lett 14(6):1674–1683CrossRef

Jarju JJ, Figueiredo MC, Kolen’ko YV (2021) Chapter 8—Electrocatalysis using nanomaterials. In: Wain AJ, Dickinson EJF eds, Frontiers of Nanoscience. Elsevier, p 343–420

Lee DU, Xu P, Cano ZP, Kashkooli AG, Park MG, Chen Z (2016) Recent progress and perspectives on bi-functional oxygen electrocatalysts for advanced rechargeable metal–air batteries. J Mater Chem A 4(19):7107–7134CrossRef

Li R, Wang D (2022) Superiority of dual-atom catalysts in electrocatalysis: one step further than single-atom catalysts. Adv Energy Mater 12(9):2103564CrossRef

Li Z, He H, Cao H, Sun S, Diao W, Gao D et al (2019) Atomic Co/Ni dual sites and Co/Ni alloy nanoparticles in N-doped porous Janus-like carbon frameworks for bifunctional oxygen electrocatalysis. Appl Catal B 240:112–121CrossRef

Li X, Duan S, Sharman E, Zhao Y, Yang L, Zhuo Z et al (2020) Exceeding the volcano relationship in oxygen reduction/evolution reactions using single-atom-based catalysts with dual-active-sites. J Mater Chem A 8(20):10193–10198CrossRef

Liu H, Huang Q, An W, Wang Y, Men Y, Liu S (2021) Dual-atom active sites embedded in two-dimensional C₂N for efficient CO₂ electroreduction: a computational study. J Energy Chem 61:507–516CrossRef

Ma M, Kumar A, Wang D, Wang Y, Jia Y, Zhang Y et al (2020) Boosting the bifunctional oxygen electrocatalytic performance of atomically dispersed Fe site via atomic Ni neighboring. Appl Catal B 274:119091CrossRef

Man IC, Su H-Y, Calle-Vallejo F, Hansen HA, Martínez JI, Inoglu NG et al (2011) Universality in oxygen evolution electrocatalysis on oxide surfaces. ChemCatChem 3(7):1159–1165CrossRef

Mohanapriya S, Dhanasekaran P, Selvaganesh SV (2022) Noble metal-free electrocatalysts: materials for energy applications. Noble metal-free electrocatalysts: fundamentals and recent advances in electrocatalysts for energy applications volume 1. ACS Symposium Series, vol 1431: American Chemical Society, p 73–94.

Osgood H, Devaguptapu SV, Xu H, Cho J, Wu G (2016) Transition metal (Fe Co, Ni, and Mn) oxides for oxygen reduction and evolution bifunctional catalysts in alkaline media. Nano Today 11(5):601–625CrossRef

Pedersen A, Barrio J, Li A, Jervis R, Brett DJL, Titirici MM et al (2022) Dual-Metal atom electrocatalysts: theory, synthesis, characterization, and applications. Adv Energy Mater 12(3):2102715CrossRef

Qiao B, Wang A, Yang X, Allard LF, Jiang Z, Cui Y et al (2011) Single-atom catalysis of CO oxidation using Pt1/FeOx. Nat Chem 3(8):634–641CrossRef

Smolinka T, Bergmann H, Garche J, Kusnezoff M (2022) Chapter 4—tThe history of water electrolysis from its beginnings to the present. In: Smolinka T, Garche J (eds) Electrochemical power sources: fundamentals, systems, and applications. Elsevier, pp 83–164CrossRef

Wang H-F, Chen L, Pang H, Kaskel S, Xu Q (2020a) MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions. Chem Soc Rev 49(5):1414–1448CrossRef

Wang K, Wang X, Li Z, Yang B, Ling M, Gao X et al (2020b) Designing 3d dual transition metal electrocatalysts for oxygen evolution reaction in alkaline electrolyte: beyond oxides. Nano Energy 77:105162CrossRef

Wang Y, Kumar A, Ma M, Jia Y, Wang Y, Zhang Y et al (2020c) Hierarchical peony-like FeCo–NC with conductive network and highly active sites as efficient electrocatalyst for rechargeable Zn-air battery. Nano Res 13(4):1090–1099CrossRef

Wang J, Xu R, Sun Y, Liu Q, Xia M, Li Y et al (2021) Identifying the Zn–Co binary as a robust bifunctional electrocatalyst in oxygen reduction and evolution reactions via shifting the apexes of the volcano plot. J Energy Chem 55:162–168CrossRef

Wang J, Zhao C-X, Liu J-N, Song Y-W, Huang J-Q, Li B-Q (2022) Dual-atom catalysts for oxygen electrocatalysis. Nano Energy 104:107927CrossRef

Wei B, Fu Z, Legut D, Germann TC, Du S, Zhang H et al (2021a) Rational design of highly stable and active MXene-Based Bifunctional ORR/OER Double-Atom Catalysts. Adv Mater 33(40):2102595CrossRef

Wei T, Ding P, Wang T, Liu L-M, An X, Yu X (2021b) Facet-Regulating local coordination of dual-atom cocatalyzed TiO₂ for photocatalytic water splitting. ACS Catal 11(23):14669–14676CrossRef

Wu C, Zhang X, Xia Z, Shu M, Li H, Xu X et al (2019) Insight into the role of Ni–Fe dual sites in the oxygen evolution reaction based on atomically metal-doped polymeric carbon nitride. J Mater Chem A 7(23):14001–14010CrossRef

Wu Y, Ye C, Yu L, Liu Y, Huang J, Bi J et al (2022) Soft template-directed interlayer confinement synthesis of a Fe-Co dual single-atom catalyst for Zn-air batteries. Energy Storage Mater 45:805–813CrossRef

Wu Y-j, Wu X-h, Tu T-X, Zhang P-F, Li J-T, Zhou Y et al (2020) Controlled synthesis of FeNx-CoNx dual active sites interfaced with metallic Co nanoparticles as bifunctional oxygen electrocatalysts for rechargeable Zn-air batteries. Appl Catalysis B: Environ 278:119259

Yasin G, Ali S, Ibraheem S, Kumar A, Tabish M, Mushtaq MA et al (2023) Simultaneously engineering the synergistic-effects and coordination-environment of dual-single-atomic Iron/Cobalt-sites as a bifunctional oxygen electrocatalyst for rechargeable Zinc-air batteries. ACS Catal 13(4):2313–2325CrossRef

Zhang L, Fischer JMTA, Jia Y, Yan X, Xu W, Wang X et al (2018) Coordination of atomic Co–Pt coupling species at carbon defects as active sites for oxygen reduction reaction. J Am Chem Soc 140(34):10757–10763CrossRef

Zhang W, Chao Y, Zhang W, Zhou J, Lv F, Wang K et al (2021) Emerging dual-atomic-site catalysts for efficient energy catalysis. Adv Mater 33(36):2102576CrossRef

Zhao S, Yan L, Luo H, Mustain W, Xu H (2018) Recent progress and perspectives of bifunctional oxygen reduction/evolution catalyst development for regenerative anion exchange membrane fuel cells. Nano Energy 47:172–198CrossRef

Zhu X, Zhang D, Chen C-J, Zhang Q, Liu R-S, Xia Z et al (2020) Harnessing the interplay of Fe–Ni atom pairs embedded in nitrogen-doped carbon for bifunctional oxygen electrocatalysis. Nano Energy 71:104597CrossRef

Title: Dual-Atom Catalysts for Oxygen Evolution Reaction
Authors: Hamid Dehghan-Manshadi
Mohammad Mazloum-Ardakani
Soraya Ghayempour
Publisher: Springer Nature Switzerland
Book: Atomically Precise Electrocatalysts for Electrochemical Energy Applications
Print ISBN: 978-3-031-54621-1

Electronic ISBN: 978-3-031-54622-8

Copyright Year: 2024
DOI: https://doi.org/10.1007/978-3-031-54622-8_12