Skip to main content
Top

2024 | OriginalPaper | Chapter

Multi-atom Catalysts for Metal-Sulfur Batteries

Authors : V. Arul, K. Radhakrishnan, B. Yogeshwari

Published in: Atomically Precise Electrocatalysts for Electrochemical Energy Applications

Publisher: Springer Nature Switzerland

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Metal-sulfur batteries offer promising energy density and cost-effectiveness, yet grapple with challenges like limited conductivity and rapid capacity degradation. The advent of multi-atom catalysts has revolutionized these batteries, addressing these issues. This chapter explores the design, synthesis, and performance of such catalysts, initiating with an overview of the challenges faced by metal-sulfur batteries and the necessity for enhanced catalysts. It delves into multi-atom catalysts, emphasizing their distinctive features and synthesis methods. The intricate interplay between composition, morphology, and structure is scrutinized for effective catalyst design. Advanced characterization approaches are highlighted for comprehending electrochemical behavior. The chapter discusses contemporary research showcasing the transformative potential of multi-atom catalysts in metal-sulfur batteries, encompassing catalytic activity, charge transfer kinetics, polysulfide conversion, and cycling stability. The conclusion addresses future prospects and challenges, underscoring the continual need for research to optimize catalyst design, scalability, and long-term stability for practical integration into large-scale energy storage systems. In summary, the chapter serves as a substantial resource for academia and engineering, providing a comprehensive overview of the pivotal role played by multi-atom catalysts in advancing metal-sulfur battery technology.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Ahmed MS, Lee S, Agostini M, Jeong MG, Jung HG, Ming J, Sun YK, Kim J, Hwang JY (2021) Multiscale understanding of covalently fixed sulfur–polyacrylonitrile composite as advanced cathode for metal–sulfur batteries. Adv Sci 8(21):2101123 Ahmed MS, Lee S, Agostini M, Jeong MG, Jung HG, Ming J, Sun YK, Kim J, Hwang JY (2021) Multiscale understanding of covalently fixed sulfur–polyacrylonitrile composite as advanced cathode for metal–sulfur batteries. Adv Sci 8(21):2101123
go back to reference Ahmed MD, Maraz KM (2023) Revolutionizing energy storage: overcoming challenges and unleashing the potential of next generation Lithium-ion battery technology. Mater Eng Res 5(1):265–278 Ahmed MD, Maraz KM (2023) Revolutionizing energy storage: overcoming challenges and unleashing the potential of next generation Lithium-ion battery technology. Mater Eng Res 5(1):265–278
go back to reference Arul V, Chandrasekaran P, Sivaraman G, Sethuraman MG (2023a) Biogenic preparation of undoped and heteroatoms doped carbon dots: effect of heteroatoms doping in fluorescence, catalytic ability and multicolour in-vitro bio-imaging applications–a comparative study. Mater Res Bull 162:112204 Arul V, Chandrasekaran P, Sivaraman G, Sethuraman MG (2023a) Biogenic preparation of undoped and heteroatoms doped carbon dots: effect of heteroatoms doping in fluorescence, catalytic ability and multicolour in-vitro bio-imaging applications–a comparative study. Mater Res Bull 162:112204
go back to reference Arul V, Sampathkumar N, Kotteeswaran S, Arul P, Aljuwayid AM, Habila MA, Govindasamy M (2023b) Biomass derived nitrogen functionalized carbon nanodots for nanomolar determination of levofloxacin in pharmaceutical and water samples. Microchim Acta 190(6):242 Arul V, Sampathkumar N, Kotteeswaran S, Arul P, Aljuwayid AM, Habila MA, Govindasamy M (2023b) Biomass derived nitrogen functionalized carbon nanodots for nanomolar determination of levofloxacin in pharmaceutical and water samples. Microchim Acta 190(6):242
go back to reference Baumann AE, Burns DA, Liu B, Thoi VS (2019) Metal-organic framework functionalization and design strategies for advanced electrochemical energy storage devices. Commun Chem 2(1):86 Baumann AE, Burns DA, Liu B, Thoi VS (2019) Metal-organic framework functionalization and design strategies for advanced electrochemical energy storage devices. Commun Chem 2(1):86
go back to reference Bhardwaj RK, Zitoun D (2023) Recent progress in solid electrolytes for all-solid-state metal (Li/Na)–sulfur batteries. Batteries 9(2):110 Bhardwaj RK, Zitoun D (2023) Recent progress in solid electrolytes for all-solid-state metal (Li/Na)–sulfur batteries. Batteries 9(2):110
go back to reference Cengiz EC, Salihoglu O, Ozturk O, Kocabas C, Demir-Cakan R (2019) Ultra-lightweight chemical vapor deposition grown multilayered graphene coatings on paper separator as interlayer in lithium-sulfur batteries. J Alloys Compd 777:1017–1024 Cengiz EC, Salihoglu O, Ozturk O, Kocabas C, Demir-Cakan R (2019) Ultra-lightweight chemical vapor deposition grown multilayered graphene coatings on paper separator as interlayer in lithium-sulfur batteries. J Alloys Compd 777:1017–1024
go back to reference Chen R, Li Q, Yu X, Chen L, Li H (2019) Approaching practically accessible solid-state batteries: stability issues related to solid electrolytes and interfaces. Chem Rev 120(14):6820–6877 Chen R, Li Q, Yu X, Chen L, Li H (2019) Approaching practically accessible solid-state batteries: stability issues related to solid electrolytes and interfaces. Chem Rev 120(14):6820–6877
go back to reference Dong Y, Cai D, Li T, Yang S, Zhou X, Ge Y, Tang H, Nie H, Yang Z (2022) Sulfur reduction catalyst design inspired by elemental periodic expansion concept for lithium–sulfur batteries. ACS Nano 16(4):6414–6425 Dong Y, Cai D, Li T, Yang S, Zhou X, Ge Y, Tang H, Nie H, Yang Z (2022) Sulfur reduction catalyst design inspired by elemental periodic expansion concept for lithium–sulfur batteries. ACS Nano 16(4):6414–6425
go back to reference Du W, Shen K, Qi Y, Gao W, Tao M, Du G, Bao SJ, Chen M, Chen Y, Xu M (2021) Efficient catalytic conversion of polysulfides by biomimetic design of “branch-leaf” electrode for high-energy sodium–sulfur batteries. Nano-Micro Lett 13:1–3 Du W, Shen K, Qi Y, Gao W, Tao M, Du G, Bao SJ, Chen M, Chen Y, Xu M (2021) Efficient catalytic conversion of polysulfides by biomimetic design of “branch-leaf” electrode for high-energy sodium–sulfur batteries. Nano-Micro Lett 13:1–3
go back to reference Eng AY, Kumar V, Zhang Y, Luo J, Wang W, Sun Y, Li W, Seh ZW (2021) Room-temperature sodium–sulfur batteries and beyond: realizing practical high energy systems through anode, cathode, and electrolyte engineering. Adv Energy Mater 11(14):2003493 Eng AY, Kumar V, Zhang Y, Luo J, Wang W, Sun Y, Li W, Seh ZW (2021) Room-temperature sodium–sulfur batteries and beyond: realizing practical high energy systems through anode, cathode, and electrolyte engineering. Adv Energy Mater 11(14):2003493
go back to reference Fang R, Xu J, Wang DW (2020) Covalent fixing of sulfur in metal–sulfur batteries. Energy Environ Sci 13(2):432–471 Fang R, Xu J, Wang DW (2020) Covalent fixing of sulfur in metal–sulfur batteries. Energy Environ Sci 13(2):432–471
go back to reference Gong Y, Li J, Yang K, Li S, Xu M, Zhang G, Shi Y, Cai Q, Li H, Zhao Y (2023) Towards practical application of Li–S battery with high sulfur loading and lean electrolyte: will carbon-based hosts win this race? Nano-Micro Lett 15(1):150 Gong Y, Li J, Yang K, Li S, Xu M, Zhang G, Shi Y, Cai Q, Li H, Zhao Y (2023) Towards practical application of Li–S battery with high sulfur loading and lean electrolyte: will carbon-based hosts win this race? Nano-Micro Lett 15(1):150
go back to reference Hu L, Dai C, Lim JM, Chen Y, Lian X, Wang M, Li Y, Xiao P, Henkelman G, Xu M (2018) A highly efficient double-hierarchical sulfur host for advanced lithium–sulfur batteries. Chem Sci 9(3):666–675CrossRef Hu L, Dai C, Lim JM, Chen Y, Lian X, Wang M, Li Y, Xiao P, Henkelman G, Xu M (2018) A highly efficient double-hierarchical sulfur host for advanced lithium–sulfur batteries. Chem Sci 9(3):666–675CrossRef
go back to reference Jiang M, Wu J, Guo H, Zhang H, Zhu M, Xu X (2022) Controlled synthesis of cube-like ZnSnO3 decorated by nickel-based films and electrochemical applications on lithium-sulfur batteries. Compos Interfaces 29(11):1217–1228 Jiang M, Wu J, Guo H, Zhang H, Zhu M, Xu X (2022) Controlled synthesis of cube-like ZnSnO3 decorated by nickel-based films and electrochemical applications on lithium-sulfur batteries. Compos Interfaces 29(11):1217–1228
go back to reference Kaneti YV, Tang J, Salunkhe RR, Jiang X, Yu A, Wu KC, Yamauchi Y (2017) Nanoarchitectured design of porous materials and nanocomposites from metal-organic frameworks. Adv Mater 29(12):1604898 Kaneti YV, Tang J, Salunkhe RR, Jiang X, Yu A, Wu KC, Yamauchi Y (2017) Nanoarchitectured design of porous materials and nanocomposites from metal-organic frameworks. Adv Mater 29(12):1604898
go back to reference Kim SJ, Kim K, Park J, Sung YE (2019) Role and potential of metal sulfide catalysts in lithium-sulfur battery applications. ChemCatChem 11(10):2373–2387 Kim SJ, Kim K, Park J, Sung YE (2019) Role and potential of metal sulfide catalysts in lithium-sulfur battery applications. ChemCatChem 11(10):2373–2387
go back to reference Liu D, Li Z, Li X, Cheng Z, Yuan L, Huang Y (2019) Recent advances in cathode materials for room‐temperature sodium−sulfur batteries. ChemPhysChem 20(23):3164–3176 Liu D, Li Z, Li X, Cheng Z, Yuan L, Huang Y (2019) Recent advances in cathode materials for room‐temperature sodium−sulfur batteries. ChemPhysChem 20(23):3164–3176
go back to reference Liu YT, Liu S, Li GR, Yan TY, Gao XP (2020) High volumetric energy density sulfur cathode with heavy and catalytic metal oxide host for lithium–sulfur battery. Adv Sci 7(12):1903693 Liu YT, Liu S, Li GR, Yan TY, Gao XP (2020) High volumetric energy density sulfur cathode with heavy and catalytic metal oxide host for lithium–sulfur battery. Adv Sci 7(12):1903693
go back to reference Liu S, Song Z, Jin X, Mao R, Zhang T, Hu F (2022) MXenes for metal-ion and metal-sulfur batteries: synthesis, properties, and electrochemistry. Mater Rep: Energy 2(1):100077 Liu S, Song Z, Jin X, Mao R, Zhang T, Hu F (2022) MXenes for metal-ion and metal-sulfur batteries: synthesis, properties, and electrochemistry. Mater Rep: Energy 2(1):100077
go back to reference Ma L, Lv Y, Wu J, Chen Y, Jin Z (2021) Recent advances in emerging non-lithium metal–sulfur batteries: a review. Adv Energy Mater 11(24):2100770 Ma L, Lv Y, Wu J, Chen Y, Jin Z (2021) Recent advances in emerging non-lithium metal–sulfur batteries: a review. Adv Energy Mater 11(24):2100770
go back to reference Roy A, Chakrabarty N, Krishna MS, Mitra S (2022) Kinetics of polysulfide on metal-sulfur batteries. In: Sulfide and selenide based materials for emerging applications. Elsevier, pp 679–713 Roy A, Chakrabarty N, Krishna MS, Mitra S (2022) Kinetics of polysulfide on metal-sulfur batteries. In: Sulfide and selenide based materials for emerging applications. Elsevier, pp 679–713
go back to reference Salama M, Rosy AR, Yemini R, Gofer Y, Aurbach D, Noked M (2019) Metal–sulfur batteries: overview and research methods. ACS Energy Lett 4(2):436–446 Salama M, Rosy AR, Yemini R, Gofer Y, Aurbach D, Noked M (2019) Metal–sulfur batteries: overview and research methods. ACS Energy Lett 4(2):436–446
go back to reference Soni CB, Vineeth SK, Kumar V (2021) Unveiling the physiochemical aspects of the matrix in improving sulfur-loading for room-temperature sodium–sulfur batteries. Mater Adv 2(13):4165–4189 Soni CB, Vineeth SK, Kumar V (2021) Unveiling the physiochemical aspects of the matrix in improving sulfur-loading for room-temperature sodium–sulfur batteries. Mater Adv 2(13):4165–4189
go back to reference Wang R, Li M, Zhang Y, Sun K, Bao W (2022) Atomic surface modification strategy of MXene materials for high performance metal sulfur batteries. Int J Energy Res 46(9):11659–11675 Wang R, Li M, Zhang Y, Sun K, Bao W (2022) Atomic surface modification strategy of MXene materials for high performance metal sulfur batteries. Int J Energy Res 46(9):11659–11675
go back to reference Wang J, Xu J, Huang Z, Fan G. Preparation of nitrogen-doped three-dimensional hierarchical porous carbon/sulfur composite cathodes for high-performance aluminum-sulfur batteries. Fullerenes, Nanotubes, Carbon Nanostruct 29(1):39–45 Wang J, Xu J, Huang Z, Fan G. Preparation of nitrogen-doped three-dimensional hierarchical porous carbon/sulfur composite cathodes for high-performance aluminum-sulfur batteries. Fullerenes, Nanotubes, Carbon Nanostruct 29(1):39–45
go back to reference Wang L, Zhen M, Hu Z (2023) Status and prospects of electrocatalysts for lithium-sulfur battery under lean electrolyte and high sulfur loading conditions. Chem Eng J 452:139344 Wang L, Zhen M, Hu Z (2023) Status and prospects of electrocatalysts for lithium-sulfur battery under lean electrolyte and high sulfur loading conditions. Chem Eng J 452:139344
go back to reference Yan B, Li X, Bai Z, Song X, Xiong D, Zhao M, Li D, Lu S (2017) A review of atomic layer deposition providing high performance lithium sulfur batteries. J Power Sources 338:34–48 Yan B, Li X, Bai Z, Song X, Xiong D, Zhao M, Li D, Lu S (2017) A review of atomic layer deposition providing high performance lithium sulfur batteries. J Power Sources 338:34–48
go back to reference Yang K, Guo Q, Li H, Hao X, Ma Y, Yang M, Zhai T, Savilov SV, Lunin VV, Xia H (2018) Highly efficient sol-gel synthesis for ZnS@ N, S co-doped carbon nanosheets with embedded heterostructure for sodium ion batteries. J Power Sources 402:340–344 Yang K, Guo Q, Li H, Hao X, Ma Y, Yang M, Zhai T, Savilov SV, Lunin VV, Xia H (2018) Highly efficient sol-gel synthesis for ZnS@ N, S co-doped carbon nanosheets with embedded heterostructure for sodium ion batteries. J Power Sources 402:340–344
go back to reference Yao Y, Chen J, Niu R, Zhao Z, Wang X (2021) High-entropy materials: features for lithium–sulfur battery applications. Metals 13(5):833; Yan R, Ma T, Cheng M, Tao X, Yang Z, Ran F, Li S, Yin B, Cheng C, Yang W (2021) Metal–organic framework derived nanostructures as multifaceted electrodes in metal–sulfur batteries. Adv Mater 33(27):2008784 Yao Y, Chen J, Niu R, Zhao Z, Wang X (2021) High-entropy materials: features for lithium–sulfur battery applications. Metals 13(5):833; Yan R, Ma T, Cheng M, Tao X, Yang Z, Ran F, Li S, Yin B, Cheng C, Yang W (2021) Metal–organic framework derived nanostructures as multifaceted electrodes in metal–sulfur batteries. Adv Mater 33(27):2008784
go back to reference Ye Z, Jiang Y, Qian J, Li W, Feng T, Li L, Wu F, Chen R (2019) Exceptional adsorption and catalysis effects of hollow polyhedra/carbon nanotube confined CoP nanoparticles superstructures for enhanced lithium–sulfur batteries. Nano Energy 64:103965 Ye Z, Jiang Y, Qian J, Li W, Feng T, Li L, Wu F, Chen R (2019) Exceptional adsorption and catalysis effects of hollow polyhedra/carbon nanotube confined CoP nanoparticles superstructures for enhanced lithium–sulfur batteries. Nano Energy 64:103965
go back to reference Ye H, Li Y (2022) Room temperature metal–sulfur batteries: what can we learn from lithium–sulfur? InfoMat 4(5):e12291 Ye H, Li Y (2022) Room temperature metal–sulfur batteries: what can we learn from lithium–sulfur? InfoMat 4(5):e12291
go back to reference Yu X, Ding Y, Sun J (2023) Design principles for 2D transition metal dichalcogenides toward lithium−sulfur batteries. Iscience Yu X, Ding Y, Sun J (2023) Design principles for 2D transition metal dichalcogenides toward lithium−sulfur batteries. Iscience
go back to reference Yu X, Manthiram A (2021) Sustainable battery materials for next‐generation electrical energy storage. Adv Energy Sustain Res 2(5):2000102 Yu X, Manthiram A (2021) Sustainable battery materials for next‐generation electrical energy storage. Adv Energy Sustain Res 2(5):2000102
go back to reference Zeng L, Zhu J, Chu PK, Huang L, Wang J, Zhou G, Yu XF (2022) Catalytic effects of electrodes and electrolytes in metal–sulfur batteries: progress and prospective. Adv Mater 34(49):2204636 Zeng L, Zhu J, Chu PK, Huang L, Wang J, Zhou G, Yu XF (2022) Catalytic effects of electrodes and electrolytes in metal–sulfur batteries: progress and prospective. Adv Mater 34(49):2204636
go back to reference Zhang B, Zhao Y, Liu J, Wang X, Li D, Li X (2017) Impact of micro-/mesoporous carbonaceous structure on electrochemical performance of sulfur. Electrochimica Acta 248:416–424 Zhang B, Zhao Y, Liu J, Wang X, Li D, Li X (2017) Impact of micro-/mesoporous carbonaceous structure on electrochemical performance of sulfur. Electrochimica Acta 248:416–424
go back to reference Zhu R, Zheng W, Yan R, Wu M, Zhou H, He C, Liu X, Cheng C, Li S, Zhao C (2022) Modulating bond interactions and interface microenvironments between polysulfide and catalysts toward advanced metal–sulfur batteries. Adv Funct Mater 32(45):2207021 Zhu R, Zheng W, Yan R, Wu M, Zhou H, He C, Liu X, Cheng C, Li S, Zhao C (2022) Modulating bond interactions and interface microenvironments between polysulfide and catalysts toward advanced metal–sulfur batteries. Adv Funct Mater 32(45):2207021
Metadata
Title
Multi-atom Catalysts for Metal-Sulfur Batteries
Authors
V. Arul
K. Radhakrishnan
B. Yogeshwari
Copyright Year
2024
DOI
https://doi.org/10.1007/978-3-031-54622-8_23