Top

Rare Metals

Published in:

03-12-2018

Synthesis and hydrogen desorption kinetics of Mg₂FeH₆- and Mg₂CoH₅-based composites with in situ formed YH₃ and Mg₂NiH₄ nanoparticles

Authors: Can Li, Zhi-Wen Wu, Qing-An Zhang

Published in: Rare Metals | Issue 7/2023

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Mg₂FeH₆- and Mg₂CoH₅-based composites with in situ formed YH₃ and Mg₂NiH₄ nanoparticles were synthesized by ball milling of Mg₁₀YNi + 4Fe (in mole ratio) and Mg₁₀YNi + 4Co powders, respectively, at 4 MPa H₂ followed by hydrogenation at 673 K for 60 h under a hydrogen pressure of 7 MPa. It is found that the nanocrystalline YH₃ and Mg₂NiH₄ particles are indeed embedded in Mg₂FeH₆ and Mg₂CoH₅ matrixes. The hydrogen desorption rates of Mg₂FeH₆- and Mg₂CoH₅-based composites are enhanced compared to those undoped Mg₂FeH₆ and Mg₂CoH₅ hydrides, respectively, due to the synergetic catalysis of nanosized YH₃ and Mg₂NiH₄ particles. This finding provides us with an efficient and simple approach for the improvement in hydrogen desorption kinetics of Mg-based hydrogen storage materials.

previous article Ultrafine Ru nanoparticles anchored on core–shell structured zeolite-carbon for efficient catalysis of hydrogen generation

next article Manufacturing and characterizing of CCTO/SEBS dielectric elastomer as capacitive strain sensors

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

[1]

Aguey-Zinsou KF, Ares-Fernández JR. Hydrogen in magnesium: new perspectives toward functional stores. Energy Environ Sci. 2010;3(5):526.CrossRef

[2]

Sakintuna B, Lamari-Darkrim F, Hirscher M. Metal hydride materials for solid hydrogen storage: a review. Int J Hydrog Energy. 2007;32(9):1121.CrossRef

[3]

Crivello JC, Denys RV, Dornheim M, Felderhoff M, Grant DM, Huot J, Jensen TR, de Jongh P, Latroche M, Walker GS, Webb CJ, Yartys VA. Mg-based compounds for hydrogen and energy storage. Appl Phys A. 2016;122(2):85.CrossRef

[4]

Si T, Cao Y, Zhang Q, Sun D, Ouyang L, Zhu M. Enhanced hydrogen storage properties of a Mg–Ag alloy with solid dissolution of indium: a comparative study. J Mater Chem A. 2015;3(16):8581.CrossRef

[5]

Zhang Y, Zhuang X, Zhu Y, Wan N, Li L, Dong J. Synergistic effects of TiH₂ and Pd on hydrogen desorption performances of MgH₂. Int J Hydrog Energy. 2015;40(46):16338.CrossRef

[6]

Yuan J, Zhu Y, Li Y, Zhang L, Li L. Effect of multi-wall carbon nanotubes supported palladium addition on hydrogen storage properties of magnesium hydride. Int J Hydrog Energy. 2014;39(19):10184.CrossRef

[7]

Cui J, Wang H, Sun DL, Zhang QA, Zhu M. Realizing nano-confinement of magnesium for hydrogen storage using vapour transport deposition. Rare Met. 2016;35(5):401.CrossRef

[8]

Nielsen TK, Manickam K, Hirscher M, Besenbacheret F, Jensen TR. Confinement of MgH₂ nanoclusters within nanoporous aerogel scaffold materials. ACS Nano. 2009;3(11):3521.CrossRef

[9]

Kalinichenka S, Röntzsch L, Kieback B. Structural and hydrogen storage properties of melt-spun Mg–Ni–Y alloys. Int J Hydrog Energy. 2009;34(18):7749.CrossRef

[10]

Ding X, Li Y, Fang F, Sun D, Zhang Q. Hydrogen-induced magnesium–zirconium interfacial coupling: enabling fast hydrogen sorption at lower temperatures. J Mater Chem A. 2017;5(10):5067.CrossRef

[11]

Feng D, Sun H, Wang X, Zhang Y. Gaseous hydrogen storage properties of La_2-xSm_xMg₁₆Ni (x = 0 ~ 0.4) as-cast alloys. Chin J Rare Met. 2017;41(6):613.

[12]

Zhang J, Cuevas F, Zaïdi W, Bonnet JP, Aymard L, Bobet JL, Latroche M. Highlighting of a single reaction path during reactive ball milling of Mg and TM by quantitative H₂ gas sorption analysis to form ternary complex hydrides (TM = Fe Co, Ni). J Phys Chem C. 2011;115(11):4971.CrossRef

[13]

Polanski M, Nielsen TK, Cerenius Y, Bystrzycki J, Jensen TR. Synthesis and decomposition mechanisms of Mg₂FeH₆ studied by in situ synchrotron X-ray diffraction and high-pressure DSC. Int J Hydrog Energy. 2010;35(8):3578.CrossRef

[14]

Norek M, Nielsen TK, Polanski M, Kunce I, Płocinski T, Jaroszewicz LR, Cerenius Y, Jensen TR, Bystrzycki J. Synthesis and decomposition mechanisms of ternary Mg₂CoH₅ studied using in situ synchrotron X-ray diffraction. Int J Hydrog Energy. 2011;36(17):10760.CrossRef

[15]

Jongh PE, Adelhelm P. Nanosizing and nanoconfinement: new strategies towards meeting hydrogen storage goals. Chemsuschem. 2010;3(12):1332.CrossRef

[16]

Li Y, Zhou G, Fang F, Yu X, Zhang Q, Ouyang L, Zhu M, Sun D. De-/re-hydrogenation features of NaAlH₄ confined exclusively in nanopores. Acta Mater. 2011;59(4):1829.CrossRef

[17]

Paskevicius M, Sheppard DA, Buckley CE. Thermodynamic changes in mechanochemically synthesized magnesium hydride nanoparticles. J Am Chem Soc. 2010;132(14):5077.CrossRef

[18]

Li W, Li C, Ma H, Chen J. Magnesium nanowires: enhanced kinetics for hydrogen absorption and desorption. J Am Chem Soc. 2007;129(21):6710.CrossRef

[19]

Zlotea C, Oumellal Y, Hwang SJ, Ghimbeu CM, Jongh PE, Latroche M. Ultra-small MgH₂ nanoparticles embedded into an ordered microporous carbon showing rapid hydrogen sorption kinetics. J Phys Chem C. 2015;119(32):18091.CrossRef

[20]

Xia G, Tan Y, Chen X, Sun D, Guo Z, Liu HK, Ouyang L, Zhu M, Yu X. Monodisperse magnesium hydride nanoparticles uniformly self-assembled on graphene. Adv Mater. 2015;27(39):5981.CrossRef

[21]

Zhang J, Zhu Y, Lin H, Liu Y, Zhang Y, Li S, Ma Z, Li L. Metal hydride nanoparticles with ultrahigh structural stability and hydrogen storage activity derived from microencapsulated nanoconfinement. Adv Mater. 2017;29(24):1700760.CrossRef

[22]

Varin RA, Li S, Chiu C, Guo L, Morozova O, Khomenko T, Wronski Z. Nanocrystalline and non-crystalline hydrides synthesized by controlled reactive mechanical alloying/milling of Mg and Mg–X (X = Fe Co, Mn, B) systems. J Alloys Compd. 2005;404(12):494.CrossRef

[23]

Varin RA, Li S, Wronski Z, Morozova O, Khomenko T. The effect of sequential and continuous high-energy impact mode on the mechano-chemical synthesis of nanostructured complex hydride Mg₂FeH₆. J Alloys Compd. 2005;390(1–2):282.CrossRef

[24]

Wang Y, Cheng F, Li C, Tao Z, Chen J. Preparation and characterization of nanocrystalline Mg₂FeH₆. J Alloys Compd. 2010;508(2):554.CrossRef

[25]

Li S, Varin RA, Morozova O, Khomenko T. Controlled mechano-chemical synthesis of nanostructured ternary complex hydride Mg₂FeH₆ under low-energy impact mode with and without pre-milling. J Alloys Compd. 2004;384(1–2):231.CrossRef

[26]

Shao HY, Li XG. Kinetics and thermodynamics of nanostructured Mg-based hydrogen storage materials synthesized from metal nanoparticles. Adv Mater Res. 2014;924:189.CrossRef

[27]

Zhang X, Yang R, Qu J, Zhao W, Xie L, Tian W, Li X. The synthesis and hydrogen storage properties of pure nanostructured Mg₂FeH₆. Nanotechnology. 2010;21(9):095706.CrossRef

[28]

Zhang QA, Zhang LX, Wang QQ. Crystallization behavior and hydrogen storage kinetics of amorphous Mg₁₁Y₂Ni₂ alloy. J Alloys Compd. 2013;551(5):376.CrossRef

[29]

Zhang QA, Liu DD, Wang QQ, Fang F, Sun DL, Ouyang LZ, Zhu M. Superior hydrogen storage kinetics of Mg₁₂YNi alloy with a long-period stacking ordered phase. Scr Mater. 2011;65(3):233.CrossRef

[30]

Si TZ, Liu YF, Zhang QA. Hydrogen storage properties of the supersaturated Mg₁₂YNi solid solution. J Alloys Compd. 2010;507(2):489.CrossRef

[31]

Li Y, Zhang L, Zhang Q, Fang F, Sun D, Li K, Wang H, Ouyang L, Zhu M. In situ embedding of Mg₂NiH₄ and YH₃ nanoparticles into bimetallic hydride NaMgH₃ to inhibit phase segregation for enhanced hydrogen storage. J Phys Chem C. 2014;118(41):23635.CrossRef

[32]

Wu ZW, Li YT, Zhang QA. Catalytic effect of nanostructured Mg₂Ni and YH₂/YH₃ on hydrogen absorption–desorption kinetics of the Mg–Cu–H system. J Alloys Compd. 2016;685:639.CrossRef

[33]

Izumi F, Ikeda T. A rietveld-analysis programm RIETAN-98 and its applications to zeolites. Mater Sci Forum. 2000;321:198.CrossRef

[34]

Zolliker P, Yvon K, Fischer P, Schefer J. Dimagnesium cobalt (I) pentahydride, Mg₂CoH₅, containing square-pyramidal pentahydrocobaltate (4−) (CoH₅⁴⁻) anions. Inor Chem. 1985;24(24):4177.CrossRef

[35]

Bobet JL, Pechev S, Chevalier B, Darriet B. Preparation of Mg₂Co alloy by mechanical alloying Effects of the synthesis conditions on the hydrogenation characteristics. J Mater Chem. 1999;9(1):315.CrossRef

[36]

Kalinichenka S, Rontzsch L, Baehtz C, Weibgarber T, Kieback B. Hydrogen desorption properties of melt-spun and hydrogenated Mg-based alloys using in situ synchrotron X-ray diffraction and TGA. J Alloys Compd. 2011;509(S2):S629.CrossRef

[37]

Zhang QA, Jiang CJ, Liu DD. Comparative investigations on the hydrogenation characteristics and hydrogen storage kinetics of melt-spun Mg₁₀NiR (R = La, Nd and Sm) alloys. Int J Hydrog Energy. 2012;37(14):10709.CrossRef

[38]

Denys RV, Poletaev AA, Maehlen JP, Solberg JK, Tarasov BP, Yartys VA. Nanostructured rapidly solidified LaMg₁₁Ni alloy. II. In situ synchrotron X-ray diffraction studies of hydrogen absorption–desorption. Int J Hydrog Energy. 2012;7(7):5710.CrossRef

[39]

Kalinichenka S, Rontzsch L, Baehtz C, Kieback B. Hydrogen desorption kinetics of melt-spun and hydrogenated Mg₉₀Ni₁₀ and Mg₈₀Ni₁₀Y₁₀ using in situ synchrotron, X-ray diffraction and thermogravimetry. J Alloys Compd. 2010;496(1–2):608.CrossRef

[40]

Spassov T, Koster U. Hydrogenation of amorphous and nanocrystalline Mg-based alloys. J Alloys Compd. 1999;287(1):243.CrossRef

[41]

Tanaka K, Miwa T, Sasaki K, Kuroda K. TEM studies of nanostructure in melt-spun Mg–Ni–La alloy manifesting enhanced hydrogen desorbing kinetics. J Alloys Compd. 2009;478(1):308.CrossRef

[42]

Lass EA. Hydrogen storage measurements in novel Mg-based nanostructured alloys produced via rapid solidification and devitrification. Int J Hydrog Energy. 2011;36(17):10787.CrossRef

[43]

Wu Y, Lototsky MV, Solberg JK, Yartys VA, Han W, Zhou SX. Microstructure and novel hydrogen storage properties of melt-spun Mg–Ni–Mm alloys. J. Alloys Compd. 2009;477(1–2):262.CrossRef

[44]

Liang G, Boily S, Huot J, Van Neste A, Schulz R. Hydrogen absorption properties of a mechanically milled Mg–50 wt% LaNi₅ composite. J Alloys Compd. 1998;268(1–2):302.

[45]

Skripnyuk V, Buchman E, Rabkin E, Estrin Y, Popov M, Jorgensen S. The effect of equal channel angular pressing on hydrogen storage properties of a eutectic Mg–Ni alloy. J Alloys Compd. 2007;436(1–2):99.CrossRef

[46]

Zou J, Sun H, Zeng X, Ji G, Ding, W. Preparation and hydrogen storage properties of Mg-rich Mg–Ni ultrafine particles. J Nanomaterials. 2012;Article ID:592147.

[47]

Retuerto M, Alonso JA, Martinez R, Jimenez-Villacorta F, Sanchez-Benitez J, Fernandez-Diaz MT, Garcia-Ramos CA, Ruskov T. Neutron powder diffraction, X-ray absorption and Mössbauer spectroscopy on Mg₂FeH₆. Int J Hydrog Energy. 2015;40(30):9306.CrossRef

[48]

Zepon G, Leiva DR, Kaufman MJ, Figueroa SJA, Floriano R, Lamas DG, Asselli AAC, Botta WJ. Controlled mechanochemical synthesis and hydrogen desorption mechanisms of nanostructured Mg₂CoH₅. Int J Hydrog Energy. 2015;40(3):1504.CrossRef

[49]

Reich JM, Wang LL, Johnson DD. Surface and particle-size effects on hydrogen desorption from catalyst-doped MgH₂. J Phys Chem C. 2012;116(38):20315.CrossRef

Title: Synthesis and hydrogen desorption kinetics of Mg2FeH6- and Mg2CoH5-based composites with in situ formed YH3 and Mg2NiH4 nanoparticles
Authors: Can Li
Zhi-Wen Wu
Qing-An Zhang
Publication date: 03-12-2018
Publisher: Nonferrous Metals Society of China
Published in: Rare Metals / Issue 7/2023
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-018-1174-z

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 7/2023

Corrosion resistance of Cr2O3 coating formed by in-situ oxidation on 2205 duplex stainless steel in different pH solutions

Surface modifications of layered LiNixMnyCozO2 cathodes via atomic and molecular layer deposition

Quasi-static and dynamic plastic deformation behavior in titanium with vanadium addition

Formation of novel TRIP-ductilized bulk metallic glass composites by manipulating nucleation kinetics via minor alloying

Ultrafine Ru nanoparticles anchored on core–shell structured zeolite-carbon for efficient catalysis of hydrogen generation

Shearing-force-driven delamination of waste residue into oxidatively stable MXene composites for high-performance Si anode

Premium Partners