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Journal of Sol-Gel Science and Technology

10.05.2024 | Original Paper

Preparation, characterization, and mechanism for enhanced photocatalytic performance in Bi1-xSmxFeO3 nanoparticles

verfasst von: Chuanfu Huang, Yao Nie, Runzhi Han, Xiufen Yang, Lei Zhuang, Jing Wang, Xiuwen Xi, Jianguo Wan

Erschienen in: Journal of Sol-Gel Science and Technology

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Abstract

Via a simple sol-gel approach, the high photocatalytic efficiency of Bi1-xSmxFeO3 nanoparticles were realized when x was 0, 0.05, 0.10, 0.15 and 0.20. Microstructural characterizations including X-ray diffraction (XRD) spectroscopy, Raman spectroscopy, field emission scanning electron microscope (FESEM), x-ray photoelectron spectroscopy (XPS) and ultraviolet-visible (UV-Vis) spectrophotometer, demonstrated a transformation from the rhombohedral structure of BiFeO3 to the orthorhombic structure of Bi0.80Sm0.20FeO3. Moreover, the experimental findings discovered that the photocatalytic efficiency of Bi0.80Sm0.20FeO3 was the highest, reaching 98.5% within 2 h based on visible light degradation. The underlying mechanisms, involved to phase transition, size effect, band energy and Fenton reaction, were discussed. The research presented in the paper is crucial in offering a fundamental strategy for utilizing BiFeO3 to address the issue of water pollutants.

Graphical Abstract

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Metadaten
Titel
Preparation, characterization, and mechanism for enhanced photocatalytic performance in Bi1-xSmxFeO3 nanoparticles
verfasst von
Chuanfu Huang
Yao Nie
Runzhi Han
Xiufen Yang
Lei Zhuang
Jing Wang
Xiuwen Xi
Jianguo Wan
Publikationsdatum
10.05.2024
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-024-06392-y

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